Fundamental Studies on Palladium Catalysts. IX. Characteristics of Hydrogen Sorption and Hydrogenation Activity of Supported Palladium Catalysts

Synthesis of Supported Palladium Catalysts

The synthesis of supported palladium (Pd) catalysts is reviewed with emphasis on the chemistry of catalyst synthesis, oxidic and carbon support properties and case studies in the period 1990-2000. For the application of Pd onto oxidic supports aqueous precursor solutions are frequently used. The charge of the Pd precursor and the iso-electric point of the support are important properties since ...

Continuous flow hydrogenation using polysilane-supported palladium/alumina hybrid catalysts

Continuous flow systems for hydrogenation using polysilane-supported palladium/alumina (Pd/(PSi-Al(2)O(3))) hybrid catalysts were developed. Our original Pd/(PSi-Al(2)O(3)) catalysts were used successfully in these systems and the hydrogenation of unsaturated C-C bonds and a nitro group, deprotection of a carbobenzyloxy (Cbz) group, and a dehalogenation reaction proceeded smoothly. The catalyst...

Recovery of Palladium from Spent Activated Carbon-Supported Palladium Catalysts

TÜBİTAK Marmara Research Center, Chemistry Institute, 41470 Gebze, Kocaeli, Turkey Email: [email protected] Activated carbon-supported palladium catalysts are liable to progressive deactivation even in the absence of any gaseous contaminants during the oxidation of hydrogen under ambient conditions. The high value of palladium coupled with environmental considerations means that n...

High-pressure X-ray photoelectron spectroscopy on palladium model hydrogenation catalysts Part2: Hydrogenation of trans-2-pentene on palladium

We have performed the first “high-pressure” XPS study on the palladium, hydrogen and olefin (trans-2-pentene) system in order to gain a better insight into the hydrogenation reaction. We report here data collected using a Pd(111) single crystal and a polycrystalline foil. Hydrogenation was observed on polycrystalline foil (RT and 373 K), but not on Pd(111) single crystal, revealed by on-line ma...

Method Of Forming Supported Doped Palladium Containing Oxidation Catalysts